Synthesis of L-cladinose using enantioselective desymmetrization.

[摘要]：L-Cladinose (I), a neutral sugar found in erythromycins and azithromycins, was synthesized efficiently using enantioselective monobenzoylation of 2-propenylglycerol in the presence of imine-CuCl2 catalysts to elaborate the stereogenic quaternary center.

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