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[摘要]：Two new complexes, [Cu2(C3N3O3H2)4]譎2O (1) (C3N3O3H2 = iso-cyanuric acid), and [Zn(C3N3O3H2)2(H2O)4] 證3N3O3H3譎2O (2), were synthesized by the reactions of cyanuric chloride (C3N3Cl3), melamine (C3N6H6) with CuCl2?H2O and ZnCl2, resp., through hydrothermal route. They were characterized by single crystal diffraction, elemental anal., thermal gravimetry anal. Also, the photoluminescent properties of both 1 and 2 were studied. In (1), the Cu(II) is two coordinated in a linear fashion by two nitrogen atoms. The Zn(II) atom in (2) is surrounded by two nitrogen atoms and four oxygen atoms to complete a six-coordinate environment. The combination of hydrogen bonds and p鬃鬃p stacking interactions extends complex (1), (2) into three-dimension architectures. |
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