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Large Stokes Shift Induced by Intramolcular Charge Transfer in N,O-Chelated Naphthyridine-BF2 Complexes

  作者 WU YUNYING; CHEN YONG; GOU GAOZHANG; MU WEIHUA; LV XIAOJUN; DU MEILING; FU WENFU  
  选自 期刊  Organic Letters;  卷期  2012年14-20;  页码  5226-5229  
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[摘要]Novel N,O-chelated naphthyridine-BF2 complexes with push-pull structures have been synthesized and characterized. Spectral investigations on these complexes reveal that photoinduced intramolecular charge transfer occurs and results in a large Stokes shift, which is further supported by density functional theory based theoretical calculations,

 
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