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Pd-Diimine: A Highly Selective Catalyst System for the Base-Free Oxidative Heck Reaction

  作者 GOTTUMUKKALA ADITYA L; TEICHERT JOHANNES F; HEIJNEN DONIS; EISINK NIEK; VAN DIJK SIMON; FERRER CATALINA; VAN DEN HOOGENBAND ADRI; MINNAARD ADRIAAN J  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-9;  页码  3498-3501  
  关联知识点  
 

[摘要]Pd(OAc)(2)/3 is an efficient catalyst system for the base-free oxidative Heck reaction that outperforms the currently available catalysts for the more challenging substrates studied. The catalyst system is highly selective, and works at room temperature with dioxygen as the oxidant.

 
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