Substrate-Controlled Stereoselective Synthesis of Ophiocerin C

[摘要]：A novel stereoselective total synthesis of ophiocerin C was accomplished starting from L-(+)- tartaric acid. The C3, C4 vic-diol moiety was obtained from tartaric acid, and the stereogenic centre at C6 was created by substrate-controlled epoxidation and subsequent regioselective cleavage of the epoxide ring.

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