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Diols and anions can control the formation of an exciplex between a pyridinium boronic acid with an aryl group connected via a propylene linker

  作者 HUANG YANJUN; JIANG YUNBAO; BULL STEVEN D; FOSSEY JOHN S; JAMES TONY D  
  选自 期刊  Chemical Communications;  卷期  2010年46-43;  页码  8180-8182  
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[摘要]The exciplex formation between a pyridinium boronic acid and phenyl group connected via a propylene linker can be monitored using fluorescence. Addition of pinacol affords a cyclic boronate ester with enhanced Lewis acidity that increases the strength of its cation-pi stacking interaction causing a four-fold fluorescence enhancement.

 
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