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Synthesis and structural analysis of a novel iodinated cyclopentadienone via ring-contraction iodination and its application in synthesis of alkyne-functionalized cyclopentadienones

  作者 CHEN XUEYI; BARNES CHARLES; BAI XINYAN; SANDRECZKI T C; PENG ZHONGHUA; KADNIKOVA EKATERINA N; DIAS J R  
  选自 期刊  Chemical Communications;  卷期  2010年46-43;  页码  8171-8173  
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[摘要]The first iodinated cyclopentadienone was isolated and its structure was confirmed by single crystal X-ray analysis. Based on this intermediate, the first direct C-C bond formation on cyclopentadienone ring was achieved. The photo induced intramolecular charge transfer of alkynylated cyclopentadienones was evaluated by solvent polarity effect on their electronic absorption spectra.

 
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