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Synthesis, characterization and property of a mixed-valent Ag-I/Ag-II coordination polymer

  作者 SUN DI; YANG CHENGFENG; XU HAORAN; ZHAO HAIXIA; WEI ZHANHUA; ZHANG NA; YU LAJIA; HUANG RONGBIN; ZHENG LANSUN  
  选自 期刊  Chemical Communications;  卷期  2010年46-43;  页码  8168-8170  
  关联知识点  
 

[摘要]A novel mixed-valent Ag-I/Ag-II coordination polymer {[(Ag2Ag0.5II)-Ag-I(SO4)(HSO4)(pyz)(2.5)]center dot H2O}(n) (1, pyz = pyrazine) was synthesized and characterized. The results show it presents semiconducting and photoluminescent properties.

 
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