Synthesis, characterization and property of a mixed-valent Ag-I/Ag-II coordination polymer
[摘要]:A novel mixed-valent Ag-I/Ag-II coordination polymer {[(Ag2Ag0.5II)-Ag-I(SO4)(HSO4)(pyz)(2.5)]center dot H2O}(n) (1, pyz = pyrazine) was synthesized and characterized. The results show it presents semiconducting and photoluminescent properties.
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