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Regioselective Protection of Sugars Catalyzed by Dimethyltin Dichloride.

  作者 Demizu, Yosuke;Kubo, Yuki;Miyoshi, Hiroko;Maki, Toshihide;Matsumura, Yoshihiro;Moriyama, Noriaki;Onomura, Osamu;  
  选自 期刊  Organic Letters;  卷期  2008年10-21;  页码  5075-5077  
  关联知识点  
 

[摘要]has been developed. Highly regioselective protection was accomplished along with high chem. yield. The regioselectivity of the benzoylation was realized as an intrinsic character of sugars based on a stereorelationship among their hydroxyl groups. Furthermore, complete protection of a-Me glucoside and b-Me xyloside was accomplished.

 
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