Titanocene(III)-Catalyzed Formation of Indolines and Azaindolines.

[摘要]：Reductive cyclization of epoxides tethered to substituted anilines and aminopyridines in the presence of 3 mol % of titanocene dichloride and stoichiometric manganese metal promotes a radical annulation to form 3,3-disubstituted indolines, e.g., I, and azaindoline II.

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