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Copper-Catalyzed Electrophilic Amination of Arylsilanes with Hydroxylamines

  作者 MIKI YUYA; HIRANO KOJI; SATOH TETSUYA; MIURA MASAHIRO  
  选自 期刊  Organic Letters;  卷期  2013年15-1;  页码  172-175  
  关联知识点  
 

[摘要]A copper-catalyzed electrophilic amination of aryl[(2-hydroxymethyl)phenyl]dimethylsilanes with O-acylated hydroxylamines has been developed to afford the corresponding anilines in good yields. The catalytic reaction proceeds very smoothly under mild conditions and tolerates a wide range of functional groups.

 
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