STEREOSPECIFIC SYNTHESIS OF trans-1,4-DIPHOSPHACYCLOHEXANES

[摘要]：Stereospecific synthesis of trans-1,4-diphosphacyclohexanes via intramolecular oxidative coupling of P-stereogenic bisphosphine borane complexes is reported. Regardless of the enantiopurity of the starting materials, only trans-isomers were formed. The synthesis and characterization of the obtained products are described in detail herein.

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