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Co(acac)(2)-Catalyzed Allylic and Benzylic Oxidation by tert-Butyl Hydroperoxide

  作者 HAN XIAOQIANG; ZHOU ZIYUAN; WAN CHUAN; XIAO YUMEI; QIN ZHAOHAI  
  选自 期刊  Synthesis;  卷期  2013年45-5;  页码  615-620  
  关联知识点  
 

[摘要]Various allylic and benzylic substrates were oxidized to the corresponding enones, arenealdehydes and aryl ketones in good yields with tert-butyl hydroperoxide in the presence of catalytic amounts of Co(acac)(2) under mild conditions. The reactivity, selectivity, and scope of the reaction were investigated.

 
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