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Cul-Nanoparticles-Catalyzed Selective Synthesis of Phenols, Anilines, and Thiophenols from Aryl Halides in Aqueous Solution

  作者 XU HUAJIAN; LIANG YUFENG; CAI ZHENYA; QI HONGXIA; YANG CHUNYAN; FENG YISI  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-7;  页码  2296-2300  
  关联知识点  
 

[摘要]CuI-nanoparticles-catalyzed selective synthesis of phenols, anilines, and thiophenols from aryl halides was developed in the absence of both ligands and organic solvents. Anilines were formed selectively with ammonia competing with hydroxylation and thiophenols were generated selectively with sulfur powder after subsequent reduction competing with hydroxylation and amination.

 
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