[摘要]：A selective anodic oxidn. system in which a carbocation intermediate is generated exclusively using a temp.-controlled multiphase soln. to sep. the different stages of the reaction from each other and from the products is described. The formation of a thermomorphic middle layer in an electrolytic soln. composed of c-Hex (cyclohexane) and LPC/MeNO2 (LPC = LiClO4) results in enhanced interaction between aliph. alkenes and polar unstable cation. The upper product-assembly phase was cyclohexane with cycloalkane-based thermomorphic phase in middle and bottom electrolytic phase of LiClO4/MeNO2.
