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Transmetallation from aluminum to tin: A facile preparation of tributylstannylprop-2-en-1-ols

  作者 Havranek, M; Dvorak, D  
  选自 期刊  Synthesis;  卷期  1998年-9;  页码  1264-1268  
  关联知识点  
 

[摘要]3-Substituted 3-tributylstannylprop-2-en-1-ols 2 can be efficiently prepared by hydroalumination of 3-substituted propargyl alcohols 1 with LiAlH4 and subsequent transmetallation to tin employing Bu3SnOMe instead of the commonly used Bu3SnOTf or Bu3SnCl.

 
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