Thieme Chemistry Journal Awardees - Where are They Now? Synthesis of the Marine Glycolipid Dioctadecanoyl Discoside

[摘要]：The first synthesis of the inositol-containing marine glycolipid dioctadecanoyl discoside is reported. The key glycosylation reaction proceeds with beta-selectivity at reduced temperature. The separable anomers could be readily progressed to afford discoside, its peracetate and the unnatural beta-derivatives.

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