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Helicity Control of an Indolocarbazole Foldamer by Chiral Organic Anions

  作者 SUK JAEMIN; KIM DAN A; JEONG KYUSUNG  
  选自 期刊  Organic Letters;  卷期  2012年14-19;  页码  5018-5021  
  关联知识点  
 

[摘要]Chiral organic anions such as camphorsulfonates and cAMP give rise to the preferential formation of a one-handed helix of an indolocarbazole foldamer, thus inducing characteristic circular dichroic (CD) signals. Moreover, the on and off switching of the chiroptical signal can be operated by acid and base chemistry which efficiently controls the association and dissipation of the foldamer and cAMP.

 
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