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Highly Chemoselective Rearrangement of 3-Aryloxaziridines to Nitrones or Amides

  作者 XING DONG; XU XINFANG; YANG LIPING  
  选自 期刊  Synthesis;  卷期  2009年-20;  页码  3399-3404  
  关联知识点  
 

[摘要]An efficient method for the chemoselective ring-opening rearrangement of 3-aryloxaziridines by using silver triflate alone to afford nitrones, or in the presence of a simple Bronsted acid to yield amides, has been developed. Silver triflate plays an important role in both transformations.

 
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