Stereoselective Synthesis of (-)-PF1163A via Prins Cyclization

[摘要]：A highly stereoselective and convergent total synthesis of PF1163 A is described while proving the versatility of Prins cyclization in natural product synthesis. The Prins cyclization, Yamaguchi esterification, and ring-closing metathesis reactions are the key steps utilized in the synthesis of macrolactone.

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