Indium-Catalyzed N-Formylation of Amines under Solvent-Free Conditions

[摘要]：We have developed a simple, mild method for N-formylation of a wide variety of amines in the presence of indium metal as a catalyst under solvent-free conditions. This reaction is applicable to the chemoselective N-formylation of amino groups and alpha-amino acid esters without epimerization.

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