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Heterocoupling of 2-naphthols enabled by a copper-N-heterocyclic carbene complex

  作者 HOLTZMULHOLLAND MICHAEL; DE LESELEUC MYLENE; COLLINS SHAWN K  
  选自 期刊  Chemical Communications;  卷期  2013年49-18;  页码  1835-1837  
  关联知识点  
 

[摘要]The reactivity of a Cu catalyst for oxidative coupling ismodulated by a small molecule additive, diethyl malonate, that slows over-oxidation of 2-naphthols. Efficient heterocoupling between electron-rich and electron-poor 2-naphthols/2-naphthylamines affords C-1-symmetric BINOLs with yields ranging from 35-98%.

 
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