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Catalytic Decarboxylative Reactions: Biomimetic Approaches Inspired by Polyketide Biosynthesis

  作者 PAN YUANHANG; TAN CHOONHONG  
  选自 期刊  Synthesis;  卷期  2011年-13;  页码  2044-2053  
  关联知识点  
 

[摘要]This short review summarizes decarboxylative reactions of malonic acid half thio/oxyester mediated by metal complexes and organocatalysts. These biomimetic reactions are inspired by similar reactions catalyzed by polyketide synthase. While they have been known for several decades, this is the first review of these reactions.

 
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