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Regioselective Carboindation of Simple Alkenes with Indium Tribromide and Ketene Silyl Acetals

  作者 NISHIMOTO YOSHIHIRO; UEDA HIROKI; INAMOTO YOSHIHIRO; YASUDA MAKOTO; BABA AKIO  
  选自 期刊  Organic Letters;  卷期  2010年12-15;  页码  3390-3393  
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[摘要]The regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals was accomplished. Various alkenes such as ethylene, 1-alkenes, and cyclic alkenes were applicable for this reaction system. The alkylindium product from the carboindation of cyclohexene revealed an anti addition mechanism.

 
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