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A Stable Heptacene Derivative Substituted With Electron-Deficient Trifluoromethylphenyl and Triisopropylsilylethynyl Groups

  作者 QU HEMI; CHI CHUNYAN  
  选自 期刊  Organic Letters;  卷期  2010年12-15;  页码  3360-3363  
  关联知识点  
 

[摘要]A heptacene derivative 1 substituted with four electron-deficient trifluoromethylphenyl and two triisopropylsilylethynyl (TIPSE) groups was prepared by a new synthetic strategy. Photo-oxidative resistance studies showed that this newly developed heptacene compound persisted 47 h in solution under ambient light and air conditions, and it represents the most stable heptacene derivative reported to date.

 
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