Phosphine-Catalyzed Tandem Reaction of Allenoates with Nitroalkenes

[摘要]：A P(p-FC6H4)(3)-catalyzed tandem reaction between ethyl 2,3-butadienoate and nitroalkenes has been developed, which involves a [3 + 2] cycloaddition and a subsequent umpolung addition. The asymmetric version of this tandem reaction has also been investigated by using chiral phosphanes.

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