Enantioselective [1,2]-Stevens rearrangement using sugar-derived alkoxides as chiral promoters.

[摘要]：The first example of enantioselective base-induced [1,2]-Stevens rearrangement was achieved by using a newly developed D-glucose-derived lithium alkoxide as a chiral promoter. This rearrangement provides an a-amino ketone having a pseudoquaternary chiral center in an enantioenriched form.

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