【文章名】Platinum-catalyzed tandem cyclization-Nazarov cylization reactions: an easy access to complex carbocyclic molecules from 2-alkenyl-(1'-hydroxyl-4-en-2-ynyl)benzenes.
Platinum-catalyzed tandem cyclization-Nazarov cylization reactions: an easy access to complex carbocyclic molecules from 2-alkenyl-(1'-hydroxyl-4-en-2-ynyl)benzenes.
作者
Abu Sohel, Shariar Md.;Lin, Sheng-Hsun;Liu, Rai-Shung;
[摘要]:In the presence of PtCl2/CO catalyst, 2-alkenyl-(1'-hydroxyl-4-en-2-ynyl)benzenes undergo a tandem electrophilic 6-exo-dig cyclization-Nazarov cyclization sequence to give 1H-cyclopenta[a]naphthalenes efficiently and regioselectively.