Diastereoselective Oxidative Carbon-Carbon Bond Formation via Silyl Bis-enol Ethers.

[摘要]：Diisopropylsilyl bis-enol ethers are shown to be powerful intermediates for the diastereoselective dimerization and cross-coupling of cyclic ketones. The trends obsd. for the oxidative coupling of a range of different dialkylsilyl bis-enol ethers derived from cyclohexanone are rationalized by invoking a stereochem. model based on a Thorpe-Ingold effect.

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