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Efficient incorporation of monomeric anthracene into nanoporous silica/surfactant nanocomposite spheres using a mechanochemical solid state reaction

  作者 TAGAYA MOTOHIRO; MOTOZUKA SATOSHI; KOBAYASHI TAKAOMI; IKOMA TOSHIYUKI; TANAKA JUNZO  
  选自 期刊  Journal of Materials Chemistry;  卷期  2012年22-36;  页码  18741-18743  
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[摘要]The incorporation of anthracene (Ant) into nanoporous silica/surfactant nanocomposite spheres was successfully achieved using a mechanochemical solid state reaction. The Ant molecules were incorporated into the nanopores while preserving the silica nanostructures, indicating the effective hydrophobic interactions with the alkyl chains of the surfactant. The blue photoluminescence intensity due to the monomer state was enhanced by increasing the mechanochemical milling force, suggesting this is an efficient preparation method for a luminescent medium by monomeric assembly of the Ant molecules.

 
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