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Gas-Phase Reactivity of Aromatic s,s-Biradicals toward Dinucleoside Phosphates.

  作者 Yang, Linan;Nash, John J.;Yurkovich, Michael J.;Jin, Zhicheng;Vinueza, Nelson R.;Kenttaemaa, Hilkka I.;  
  选自 期刊  Organic Letters;  卷期  2008年10-10;  页码  1889-1892  
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[摘要]In order to improve the understanding of the interactions of arom. s,s-biradicals with DNA, the reactivity of three isomeric s,s-biradicals toward four dinucleoside phosphates was studied in a mass spectrometer. The dinucleoside phosphates were evapd. into the mass spectrometer by using laser-induced acoustic desorption (LIAD). The results demonstrate that the structure of the s,s-biradical and the base sequence of the dinucleoside phosphate can have a major influence on these reactions.

 
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