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Controllable One-Step Synthesis of Spirocycles, Polycycles, and Di- and Tetrahydronaphthalenes from Aryl-Substituted Propargylic Alcohols.

  作者 Huang, Wen;Zheng, Pengzhi;Zhang, Zhengxing;Liu, Ruiting;Chen, Zhenxia;Zhou, Xigeng;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2008年73-17;  页码  6845-6848  
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[摘要]A novel, convenient, and efficient method has been developed for selective synthesis of spirocycle, polycycle, and di- and tetrahydronaphthalene systems from aryl-substituted propargylic alcs., e.g. I, by FeCl3- or TsOH-catalyzed multiple activations of unsatd. C-C bonds and C-H bonds.

 
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