Nickel-catalyzed cross-coupling reaction of allyl- and benzylzinc with alkenyl sulfides.

[摘要]：29, 67 Alkenyl sulfides can be utilized for nickel-catalyzed cross-coupling reactions with allyl- and benzylzinc reagents. Thus, NiCl2/P(2-furyl)3/BuLi catalyzed cross-coupling reaction of (E)-1-phenylthio-2-phenylethene with allylzinc chloride in THF gave 99% (E)-1-phenyl-1,4-pentadiene.

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