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Phosphorus-Containing Lewis Base Catalyzed Cascade Reactions of Isatin-Derived Oximes with Allenic Esters and Further Transformations

  作者 PEI CHENGKUI; JIANG YU; SHI MIN  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2012年-22;  页码  4206-4216  
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[摘要]Phosphorus containing Lewis base catalyzed cascade reactions of isatin-derived oximes with allenic esters afford the corresponding functionalized nitrones. Further Lewis acid catalyzed highly regioselective intramolecular [3+2] cyclizations give the corresponding bridged cycloadducts. Moreover, a combined one-pot reaction is also feasible for the above two catalytic reactions.

 
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