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Rapid and Regioselective Hydrogenation of alpha,beta-Unsaturated Ketones and Alkylidene Malonic Diesters Using Hantzsch Ester Catalyzed by Titanium Tetrachloride

  作者 CHE JUN; LAM YULIN  
  选自 期刊  SYNLETT;  卷期  2010年-16;  页码  2415-2420  
  关联知识点  
 

[摘要]A regioselective hydrogenation of alpha,beta-unsaturated ketones and alkylidene malonic diesters using Hantzsch ester as the reducing agent and titanium tetrachloride as a catalyst is described. The short reaction times and mild reaction conditions are the advantages of this method.

 
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