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Harnessing "Click"-Type Chemistry for the Preparation of Novel Electronic Materials

  作者 Firstenberg, M; Shivananda, KN; Cohen, I; Solomeshch, O; Medvedev, V; Tessler, N; Eichen, Y  
  选自 期刊  ADVANCED FUNCTIONAL MATERIALS;  卷期  2011年21-4;  页码  634-643  
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[摘要]Sequence-independent or "click"-type chemistry is applied for the preparation of novel pi-conjugated oligomers. A variety of bi-functional monomers for Wittig-Horner olefination are developed and applied in a sequential protection-deprotection process for the preparation of structurally similar pi-conjugated oligomers. Selected oligomers are incorporated as the organic semiconductors in light-emitting diodes and a field-effect transistor, demonstrating the potential of the approach.

 
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