个性化文献订阅>期刊> Journal of Organic Chemistry
 

Rhodium- and Iridium-Catalyzed Dehydrogenative Cyclization through Double C-H Bond Cleavages To Produce Fluorene Derivatives

  作者 ITOH MASAKI; HIRANO KOJI; SATOH TETSUYA; SHIBATA YU; TANAKA KEN; MIURA MASAHIRO  
  选自 期刊  Journal of Organic Chemistry;  卷期  2013年78-4;  页码  1365-1370  
  关联知识点  
 

[摘要]The rhodium-catalyzed cyclization of a series of 2,2-diarylalkanoic acids in the presence of copper acetate as an oxidant smoothly proceeded through double C-H bond cleavages and subsequent decarboxylation to produce the corresponding fluorene derivatives. The direct cyclization of triarylmethanols also took place efficiently by using an iridium catalyst in place of the rhodium, while the hydroxy function was still intact.

 
      被申请数(0)  
 

[全文传递流程]

一般上传文献全文的时限在1个工作日内