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Cavity-Extended Pillar[5]arenes: Syntheses and Host-Guest Complexation with Paraquat and Bispyridinium Derivatives

  作者 YU GUOCAN; ZHANG ZIBIN; HE JIUMING; ABLIZ ZEPER; HUANG FEIHE  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2012年-30;  页码  5902-5907  
  关联知识点  
 

[摘要]Cavity-extended pillar[5]arenes containing electron-rich naphthyl groups have been demonstrated to have enhanced binding affinity to linear guests containing electron-deficient pyridinium units. The importance of size effect, charge density, cooperative effect, and C-H...pi interactions were investigated, and these factors play significant roles in the complexation of these hostguest systems.

 
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