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Synthesis of Polysubstituted Naphthalenes by Iron-Catalyzed [2+2+2] Annulation of Grignard Reagents with Alkynes

  作者 ILIES LAUREAN; MATSUMOTO ARIMASA; KOBAYASHI MOTOAKI; YOSHIKAI NAOHIKO; NAKAMURA EIICHI  
  选自 期刊  SYNLETT;  卷期  2012年-16;  页码  2381-2384  
  关联知识点  
 

[摘要]Iron catalyzes the oxidative [2+2+2] annulation of an arylmagnesium compound with two molecules of an internal alkyne via C-H bond activation at 0 degrees C to produce polysubstituted naphthalene.

 
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