Triphenylphosphine as a Ligand for the Pd-Catalyzed Amination of Unactivated Aryl Chlorides with Anilines Promoted by Salicylaldimine

[摘要]：An efficient and selective amination of unactivated aryl chlorides with anilines catalyzed by mixed ligand Pd catalytic system of Ph3P-salicylaldimine has been developed for the preparation of diarylamines. The benzyne mechanism was ruled out based on experimental results.

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