- Application of 1-(3-bromo-3,3-difluoroprop-1-ynyl)benzenes in Diels-Alder reactions: synthesis of ortho-CF2Br-substituted biaryls.
[作者:Muzalevskiy, Vasiliy M.;Nenajdenko, Valentine G.;Shastin, Aleksey V.;Balenkova, Elizabeth S.;Haufe, Gunter;,期刊:Synthesis, 页码:2899-2904 , 文章类型: 研究论文,,卷期:2008年-18]
- 1-(3-Bromo-3,3-difluoroprop-1-ynyl)benzenes are good dienophiles in Diels-Alder reactions. Based on this key reaction, a new pathway towards biaryls with an ortho-CF2Br group was elaborated.
- An easy and efficient one-step procedure for the preparation of alkyl and aryl alkylcarbamates from S-methyl N-alkylthiocarbamates.
[作者:Degani, Iacopo;Fochi, Rita;Magistris, Claudio;,期刊:Synthesis, 页码:2919-2924 , 文章类型: 研究论文,,卷期:2008年-18]
- A general, 1-step procedure for the synthesis of alkyl and aryl alkylcarbamates, by the direct reaction of S-Me N-alkylthiocarbamates with alcs. or phenols in toluene at reflux in the presence of Et3N, is reported. All ...
- trans-resveratrol-d4, a molecular tracer of the wild-type phytoalexin; synthesis and spectroscopic properties.
[作者:Gabriele, Bartolo;Benabdelkamel, Hicham;Plastina, Pierluigi;Fazio, Alessia;Sindona, Giovanni;Di Donna, Leonardo;,期刊:Synthesis, 页码:2953-2956 , 文章类型: 研究论文,,卷期:2008年-18]
- A 6-step synthesis of trans-resveratrol-d4, (E)-3',4,5'-trihydroxy-2,3,5,6-tetradeuterostilbene, starting from com. available phenol-d6, with overall yield of 25%, is described. The reaction involves phenol-d6 methylati...
- Copper(I)-catalyzed three-component coupling leading to an efficient synthesis of b,g-alkynyl a-amino acid derivatives.
[作者:Shao, Zhihui;Chan, Albert S. C.;,期刊:Synthesis, 页码:2868-2870 , 文章类型: 研究论文,,卷期:2008年-18]
- The first copper(I)-catalyzed direct three-component coupling of Et glyoxylate, p-anisidine, and terminal alkynes has been developed. This protocol provides an efficient method to prep. b,g-alkynyl a-amino acid derivs. ...
- Comprehensive experimental and theoretical studies of configurationally labile epimeric diamine complexes of a-lithiated benzyl carbamates.
[作者:Lange, Heiko;Huenerbein, Robert;Wibbeling, Birgit;Froehlich, Roland;Grimme, Stefan;Hoppe, Dieter;,期刊:Synthesis, 页码:2905-2918 , 文章类型: 研究论文,,卷期:2008年-18]
- Different primary benzyl-type carbamates were deprotonated by sec-butyllithium in the presence of a tert-leucinol-derived bis(oxazoline) ligand. The resulting configurationally labile epimeric complexes equilibrated and...
- Chiral bispidines.
[作者:Breuning, Matthias;Steiner, Melanie;,期刊:Synthesis, 页码:2841-2867 , 文章类型: 研究论文,,卷期:2008年-18]
- 3,7-diazabicyclo[3.3.1]nonane framework. Their structural diversity is broad, reaching from simple bicyclic derivs. with chiral substituents at the N atoms to sophisticated tetracyclic ones like (-)-sparteine. This rev...
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