- Substituted Pyrroles via Olefin Cross-Metathesis
[作者:DONOHOE TIMOTHY J; RACE NICHOLAS J; BOWER JOHN F; CALLENS CEDRIC K A,期刊:Organic Letters, 页码:4094-4097 , 文章类型: Article,,卷期:2010年12-18]
- Olefin cross-metathesis (CM) provides a short and convenient entry to diverse trans-gamma-aminoenones. When exposed to either acid or Heck arylation conditions, these intermediates are converted to mono-, di-, or trisubs...
- Copper-Catalyzed Olefin Aminoacetoxylation
[作者:MANCHENO DANNY E; THORNTON AARON R; STOLL ARMIN H; KONG AIDI; BLAKEY SIMON B,期刊:Organic Letters, 页码:4110-4113 , 文章类型: Article,,卷期:2010年12-18]
- A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine f...
- The Electrical Properties of Biphenylenes
[作者:SCHNEEBELI SEVERIN; KAMENETSKA MARIA; FOSS FRANK; VAZQUEZ HECTOR; SKOUTA RACHID; HYBERTSEN MARK; VENKATARAMAN LATHA; BRESLOW RONALD,期刊:Organic Letters, 页码:4114-4117 , 文章类型: Article,,卷期:2010年12-18]
- The effect of the partial antiaromaticity of biphenylene on its substitution chemistry, its oxidation potential, and its single-molecule conductance is explored. Biphenylene and fluorene molecules with linkers of two ami...
- Insertion-Coupling-Cycloisomerization Domino Synthesis and Cation-Induced Halochromic Fluorescence of 2,4-Diarylpyrano[2,3-b]indoles
[作者:SCHOENHABER JAN; FRANK WALTER; MUELLER THOMAS J J,期刊:Organic Letters, 页码:4122-4125 , 文章类型: Article,,卷期:2010年12-18]
- 2,4-Diarylpyrano[2,3-b]indoles are formed via a Pd-Cu-catalyzed insertion coupling cycloisomerization domino reaction in moderate yields. Although the tricyclic systems are nonfluorescent in solution, protonation, quater...
- Total Synthesis of (-)-Apicularen A
[作者:PALIMKAR SANJAY S; UENISHI JUNICHI,期刊:Organic Letters, 页码:4160-4163 , 文章类型: Article,,卷期:2010年12-18]
- A convergent total synthesis of (-)-apicularen A, a highly cytostatic 12-membered macrolide, has been accomplished. The key steps include assembling of iodoalkene 8 and aldehyde 9 by Nozaki-Hiyama-Kishi (NHK) coupling, s...
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