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  • Substituted Pyrroles via Olefin Cross-Metathesis
    [作者:DONOHOE TIMOTHY J; RACE NICHOLAS J; BOWER JOHN F; CALLENS CEDRIC K A,期刊:Organic Letters, 页码:4094-4097 , 文章类型: Article,,卷期:2010年12-18]
  • Olefin cross-metathesis (CM) provides a short and convenient entry to diverse trans-gamma-aminoenones. When exposed to either acid or Heck arylation conditions, these intermediates are converted to mono-, di-, or trisubs...
  • Rhodium-Catalyzed Asymmetric Arylation of Azomethine Imines
    [作者:SHINTANI RYO; SOH YINGTECK; HAYASHI TAMIO,期刊:Organic Letters, 页码:4106-4109 , 文章类型: Article,,卷期:2010年12-18]
  • A rhodium-catalyzed addition of sodium tetraarylborates to azomethine imines has been described. Highly efficient asymmetric catalysis has also been achieved by employing a chiral diene ligand to give 1-(diarylmethyl)pyr...
  • Copper-Catalyzed Olefin Aminoacetoxylation
    [作者:MANCHENO DANNY E; THORNTON AARON R; STOLL ARMIN H; KONG AIDI; BLAKEY SIMON B,期刊:Organic Letters, 页码:4110-4113 , 文章类型: Article,,卷期:2010年12-18]
  • A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine f...
  • The Electrical Properties of Biphenylenes
    [作者:SCHNEEBELI SEVERIN; KAMENETSKA MARIA; FOSS FRANK; VAZQUEZ HECTOR; SKOUTA RACHID; HYBERTSEN MARK; VENKATARAMAN LATHA; BRESLOW RONALD,期刊:Organic Letters, 页码:4114-4117 , 文章类型: Article,,卷期:2010年12-18]
  • The effect of the partial antiaromaticity of biphenylene on its substitution chemistry, its oxidation potential, and its single-molecule conductance is explored. Biphenylene and fluorene molecules with linkers of two ami...
  • Base-Promoted Reaction of 5-Hydroxyuracil Derivatives with Peroxyl Radicals
    [作者:AMORATI RICCARDO; VALGIMIGLI LUCA; PEDULLI GIAN FRANCO; GRABOVSKIY STANISLAV A; KABALNOVA NATALIA N; CHATGILIALOGLU CHRYSSOSTOMOS,期刊:Organic Letters, 页码:4130-4133 , 文章类型: Article,,卷期:2010年12-18]
  • Addition of millimolar amounts of a weak base (pyridines) dramatically accelerates the reaction with peroxyl radicals of two biologically relevant uracil derivatives, 5-hydroxyuracil (HU) and 5-hydroxy-6-methyluracil (HM...
  • Total Synthesis of (-)-Apicularen A
    [作者:PALIMKAR SANJAY S; UENISHI JUNICHI,期刊:Organic Letters, 页码:4160-4163 , 文章类型: Article,,卷期:2010年12-18]
  • A convergent total synthesis of (-)-apicularen A, a highly cytostatic 12-membered macrolide, has been accomplished. The key steps include assembling of iodoalkene 8 and aldehyde 9 by Nozaki-Hiyama-Kishi (NHK) coupling, s...