- Camphor Sulfonyl Hydrazines (CaSH) as Organocatalysts in Enantioselective Diels-Alder Reactions.
[作者:He, Hao;Pei, Bao-Jian;Chou, Ho-Hsuan;Tian, Tian;Chan, Wing-Hong;Lee, Albert W. M.;,期刊:Organic Letters, 页码:2421-2424 , 文章类型: 研究论文,,卷期:2008年10-12]
- Cyclic sulfonyl hydrazine was demonstrated for the first time as a new functionality for organocatalysis. A series of six-membered cyclic hydrazines derived from camphor sulfonic acid were synthesized. With trichloroac...
- Organocatalytic Enantioselective Domino Michael-aldol Condensation of 5-Oxoalkanal and a,b-Unsaturated Aldehydes. Efficient Assembly of Densely Functionalized Cyclohexenes.
[作者:Hong, Bor-Cherng;Nimje, Roshan Y.;Sadani, Amit A.;Liao, Ju-Hsiou;,期刊:Organic Letters, 页码:2345-2348 , 文章类型: 研究论文,,卷期:2008年10-12]
- Organocatalytic Michael reaction of glutaraldehyde and 3-arylpropenals followed by the subsequent intramol. aldol condensation provided 2-arylcyclohex-3-ene-1,3-dicarbaldehydes. Reactions with 5-oxohexanal afforded high...
- Copper-Catalyzed Reaction of Alkyl Halides with Cyclopentadienylmagnesium Reagent.
[作者:Sai, Masahiro;Someya, Hidenori;Yorimitsu, Hideki;Oshima, Koichiro;,期刊:Organic Letters, 页码:2545-2547 , 文章类型: 研究论文,,卷期:2008年10-12]
- Treatment of alkyl halides, including tertiary alkyl bromides, with cyclopentadienylmagnesium bromide in the presence of a catalytic amt. of copper(II) triflate yielded the corresponding cyclopentadienylated products in ...
- Carbon Tetrabromide-Mediated Carbon-Sulfur Bond Formation via a Sulfenyl Bromide Intermediate.
[作者:Tan, Jing;Liang, Fushun;Wang, Yeming;Cheng, Xin;Liu, Qun;Yuan, Hongjuan;,期刊:Organic Letters, 页码:2485-2488 , 文章类型: 研究论文,,卷期:2008年10-12]
- xanthates, dithioesters, and thioethers were prepd. in one pot by reacting the corresponding dithioic acids or thiols with active methylene compds./indole derivs. under mild conditions. The formation of a sulfenyl bromi...
- Ariakemicins A and B, Novel Polyketide-peptide Antibiotics from a Marine Gliding Bacterium of the Genus Rapidithrix.
[作者:Oku, Naoya;Adachi, Kyoko;Matsuda, Satoru;Kasai, Hiroaki;Takatsuki, Akira;Shizuri, Yoshikazu;,期刊:Organic Letters, 页码:2481-2484 , 文章类型: 研究论文,,卷期:2008年10-12]
- Ariakemicins A (1) and B (2), unusual linear hybrid polyketide-nonribosomal peptide antibiotics, were discovered from the fermn. ext. of the marine gliding bacterium Rapidithrix sp. These metabolites were positional iso...
- Multisignal Chemosensor for Cr3+ and Its Application in Bioimaging.
[作者:Huang, Kewei;Yang, Hong;Zhou, Zhiguo;Yu, Mengxiao;Li, Fuyou;Gao, Xia;Yi, Tao;Huang, Chunhui;,期刊:Organic Letters, 页码:2557-2560 , 文章类型: 研究论文,,卷期:2008年10-12]
- A multisignal sensor based on rhodamine B with a ferrocene substituent (FD7, I) has been developed as a highly sensitive chemosensor for Cr3+. A prominent fluorescence enhancement was found in the presence of Cr3+, whic...
- Synthesis of Spiro-bisperoxyketals.
[作者:Ghorai, Prasanta;Dussault, Patrick H.;Hu, Chunhua;,期刊:Organic Letters, 页码:2401-2404 , 文章类型: 研究论文,,卷期:2008年10-12]
- Syntheses of spirocyclic bis-1,2-dioxolanes, bis-1,2-dioxanes, and bis-1,2-dioxepanes are achieved through intramol. ketalizations of hydroperoxy ketones or intramol. alkylations of gem-dihydroperoxides. The spiroperoxid...
- Benzyne click chemistry: synthesis of benzotriazoles from benzynes and azides.
[作者:Shi, Feng;Waldo, Jesse P.;Chen, Yu;Larock, Richard C.;,期刊:Organic Letters, 页码:2409-2412 , 文章类型: 研究论文,,卷期:2008年10-12]
- A variety of substituted benzotriazoles have been prepd. by the [3 + 2] cycloaddn. of azides to benzynes. The reaction scope is quite general, affording a rapid and easy entry to substituted, functionalized benzotriazol...
- Catalytic atropo-Enantioselective Reduction of Biaryl Lactones to Axially Chiral Biaryl Compounds.
[作者:Ashizawa, Tomoko;Tanaka, Saiko;Yamada, Tohru;,期刊:Organic Letters, 页码:2521-2524 , 文章类型: 研究论文,,卷期:2008年10-12]
- The atropo-enantioselective borohydride redn. with dynamic kinetic resoln. of biaryl lactones, e.g. I (R = H, Cl, Me, AcO, etc.), was catalyzed by an optically active b-ketoiminatocobalt(II) complex to afford optically a...
- Stereoselective Synthesis of 2,3-Unsaturated 1,6-Oligosaccharides by Means of a Glycal-Derived Allyl Epoxide and N-Nosyl Aziridine.
[作者:Di Bussolo, Valeria;Checchia, Lorenzo;Romano, Maria Rosaria;Pineschi, Mauro;Crotti, Paolo;,期刊:Organic Letters, 页码:2493-2496 , 文章类型: 研究论文,,卷期:2008年10-12]
- b-D-Threo- and 4-deoxy-4-amino-a-D-erythro-hex-2-enopyranosyl di- and trisaccharides with free hydroxy or amine functional groups were synthesized by means of a reiterative, completely stereoselective glycosylation proce...
- Chemical Synthesis of Cyclic Galactooligofuranosides Isolated from Enzymatic Degradation Products of Cell Wall Arabinogalactan of Mycobacterium tuberculosis.
[作者:Kim, Kwan Soo;Lee, Bo-Young;Yoon, Sung Ho;Jeon, Hyo Jin;Baek, Ju Yuel;Jeong, Kyu-Sung;,期刊:Organic Letters, 页码:2373-2376 , 文章类型: 研究论文,,卷期:2008年10-12]
- Synthesis of cyclic tetra-, hexa- and octasaccharides contg. alternating (1?)-b- and (1?)-b-galactofuranosyl linkages has been achieved by intramol. cycloglycosylation of corresponding linear sugars and by cyclooligomeri...
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