- 2-Hydroxy-5-nitrobenzyl as a Diazeniumdiolate Protecting Group: Application in NO-Releasing Polymers with Enhanced Biocompatibility.
[作者:Xu, Hua;Reynolds, Melissa M.;Cook, Keith E.;Evans, Anthony S.;Toscano, John P.;,期刊:Organic Letters, 页码:4593-4596 , 文章类型: 研究论文,,卷期:2008年10-20]
- The 2-hydroxy-5-nitrobenzyl group is shown to be an effective protecting group for diazeniumdiolates. O2-(2-Hydroxy-5-nitrobenzyl)-substituted diazeniumdiolates display enhanced thermal stability, but efficiently release...
- Enantioselective Organocatalytic Conjugate Addition of Aldehydes to Nitrodienes.
[作者:Belot, Sebastien;Massaro, Assunta;Tenti, Alice;Mordini, Alessandro;Alexakis, Alexandre;,期刊:Organic Letters, 页码:4557-4560 , 文章类型: 研究论文,,卷期:2008年10-20]
- The asym. organocatalyzed Michael addn. of aldehydes to a,b-g,d-unsatd. nitro compds. has been accomplished using only 5 mol % of (S)-diphenylprolinol silyl ether and 2 equiv of aldehyde in a mixt. of ethanol and water (...
- Mild and Efficient Re(VII)-Catalyzed Synthesis of 1,1-Dihydroperoxides.
[作者:Ghorai, Prasanta;Dussault, Patrick H.;,期刊:Organic Letters, 页码:4577-4579 , 文章类型: 研究论文,,卷期:2008年10-20]
- Re2O7 in CH3CN is a remarkably efficient and mild catalyst for the peroxyacetalization of ketones, aldehydes, or acetals by H2O2 to generate 1,1-dihydroperoxides. Me3SiOReO3 and Me rhenium trioxide (MTO) are also effect...
- Efficient Iron-Catalyzed N-Arylation of Aryl Halides with Amines.
[作者:Guo, Diliang;Huang, He;Xu, Jinyi;Jiang, Hualiang;Liu, Hong;,期刊:Organic Letters, 页码:4513-4516 , 文章类型: 研究论文,,卷期:2008年10-20]
- 22, 27, 28 A practical and promising protocol was developed for N-arylations of various amines with differently substituted aryl halides. The processes are efficiently promoted by the catalyst system involving the envir...
- General, Stereoselective Synthesis of (Z)-b,g-Unsaturated Nitriles Promoted by Samarium Diiodide.
[作者:Concellon, Jose M.;Rodriguez-Solla, Humberto;Simal, Carmen;Santos, David;Paz, Nieves R.;,期刊:Organic Letters, 页码:4549-4552 , 文章类型: 研究论文,,卷期:2008年10-20]
- A method to obtain (Z)-b,g-unsatd. nitriles in high or good yields and with moderate or high stereoselectivity is described. The products were achieved through the photoinduced metalation of 3-acetoxy-4-chloronitriles w...
- Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System.
[作者:Kawamorita, Soichiro;Hamasaka, Go;Ohmiya, Hirohisa;Hara, Kenji;Fukuoka, Atsushi;Sawamura, Masaya;,期刊:Organic Letters, 页码:4697-4700 , 文章类型: 研究论文,,卷期:2008年10-20]
- A heterogeneous mono(phosphine)-Rh catalyst system silica-SMAP-Rh(OMe)(cod), where silica-SMAP stands for a caged, compact trialkylphosphine (SMAP) supported on silica gel, showed broad applicability toward the hydrogena...
- Ruthenium-Catalyzed Stereoselective anti-Markovnikov-Addition of Thioamides to Alkynes.
[作者:Goossen, Lukas J.;Blanchot, Mathieu;Salih, Kifah S. M.;Karch, Ralf;Rivas-Nass, Andreas;,期刊:Organic Letters, 页码:4497-4499 , 文章类型: 研究论文,,卷期:2008年10-20]
- bis(2-methallyl)-cycloocta-1,5-diene-ruthenium(II) and a phosphine was found to efficiently catalyze the addn. of thioamides to terminal alkynes with exclusive formation of the anti-Markovnikov thioenamide products. The ...
- Synthesis of 3,5-Difluorotyrosine-Containing Peptides: Application in Substrate Profiling of Protein Tyrosine Phosphatases.
[作者:Gopishetty, Bhaskar;Ren, Lige;Waller, Tiffany M.;Wavreille, Anne-Sophie;Lopez, Miguel;Thakkar, Amit;Zhu, Jinge;Pei, Dehua;,期刊:Organic Letters, 页码:4605-4608 , 文章类型: 研究论文,,卷期:2008年10-20]
- efficiently prepd. by a chemoenzymic process and incorporated into individual peptides and combinatorial peptide libraries. The F2Y-contg. peptides display kinetic properties toward protein tyrosine phosphatases (PTPs) ...
- A method for detecting water in organic solvents.
[作者:Sun, Haoran;Wang, Bijia;DiMagno, Stephen G.;,期刊:Organic Letters, 页码:4413-4416 , 文章类型: 研究论文,,卷期:2008年10-20]
- The potent dehydrating ability of difluoro(aryl)-l3-iodanes is exploited to develop a convenient 19F-NMR-based aquametry method that is more sensitive than coulometric Karl Fischer titrn. The key difluoro(aryl)-l3-iodan...
- Fluorescence "Turn On" Chemosensors for Ag+ and Hg2+ Based on Tetraphenylethylene Motif Featuring Adenine and Thymine Moieties.
[作者:Liu, Lei;Zhang, Guanxin;Xiang, Junfeng;Zhang, Deqing;Zhu, Daoben;,期刊:Organic Letters, 页码:4581-4584 , 文章类型: 研究论文,,卷期:2008年10-20]
- Two new tetraphenylethylene (TPE) compds. 1 and 2 bearing adenine and thymine moieties, resp., are fluorescence turn on chemosensors for Ag+ and Hg2+ by making use of the AIE feature of TPE motif and the specific binding...
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