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  • Iron-Catalyzed Enyne Cross-Coupling Reaction.
    [作者:Hatakeyama, Takuji;Yoshimoto, Yuya;Gabriel, Toma;Nakamura, Masaharu;,期刊:Organic Letters, 页码:5341-5344 , 文章类型: 研究论文,,卷期:2008年10-23]
  • In the presence of 0.5-1 mol % of FeCl3 with lithium bromide as a crucial additive, alkynyl Grignard reagents, prepd. from the corresponding alkynes and methylmagnesium bromide, react with alkenyl bromides or triflates t...
  • Tin-Free Enantioselective Radical Reactions Using Silanes.
    [作者:Sibi, Mukund P.;Yang, Yong-Hua;Lee, Sunggi;,期刊:Organic Letters, 页码:5349-5352 , 文章类型: 研究论文,,卷期:2008年10-23]
  • Readily available hexyl silane is an excellent choice as a H-atom donor and a chain carrier in Lewis acid mediated enantioselective radical reactions. Conjugate radical addns. to a,b-unsatd. imides at room temp. proceed...
  • "Pure by NMR"?.
    [作者:Claridge, Timothy D. W.;Davies, Stephen G.;Polywka, Mario E. C.;Roberts, Paul M.;Russell, Angela J.;Savory, Edward D.;Smith, Andrew D.;,期刊:Organic Letters, 页码:5433-5436 , 文章类型: 研究论文,,卷期:2008年10-23]
  • Integration of a 13C-1H satellite peak of a given 12C-1H parent resonance within a quant. 1H NMR spectrum and comparison to the minor component represents a simple protocol for the accurate detn. of diastereoisomeric rat...
  • Biased Helical Folding of Chiral Oligoindole Foldamers.
    [作者:Naidu, Veluru Ramesh;Kim, Min Cheol;Suk, Jae-min;Kim, Ho-Joong;Lee, Myongsoo;Sim, Eunji;Jeong, Kyu-Sung;,期刊:Organic Letters, 页码:5373-5376 , 文章类型: 研究论文,,卷期:2008年10-23]
  • Oligoindole-based chiral foldamers have been synthesized by incorporating (S)- or (R)-1-phenylethylamine to both ends of the tetraindole scaffold. The oligoindoles fold into a helical conformation upon binding an anion ...
  • Turning on Fluorescent Emission from C-Alkylation on Quinoxaline Derivatives.
    [作者:Son, Ho-Jin;Han, Won-Sik;Wee, Kyung-Ryang;Yoo, Dae-Hwan;Lee, Jong-Ho;Kwon, Soon-Nam;Ko, Jaejung;Kang, Sang Ook;,期刊:Organic Letters, 页码:5401-5404 , 文章类型: 研究论文,,卷期:2008年10-23]
  • Redn. on imine moiety (C=N) of quinoxalines by alkyl-/aryllithiums led to a geometrical change on the quinoxaline ring, thereby perturbing the electronic structure to turn on fluorescence emission. Such a structural cha...
  • Electronic and Steric Effects in Binding of Deep Cavitands.
    [作者:Hooley, Richard J.;Shenoy, Siddhartha R.;Rebek, Julius, Jr.;,期刊:Organic Letters, 页码:5397-5400 , 文章类型: 研究论文,,卷期:2008年10-23]
  • A deep, self-folding cavitand responds to minor electronic differences between suitably sized adamantane guests. Binding consts. range from < 0.5 to 4000 M-1 for guests as similar as 1-bromoadamantane and 1-cyanoadamant...
  • Alkali Metals in Silica Gel (M-SG): A New Reagent for Desulfonation of Amines.
    [作者:Nandi, Partha;Redko, Mikhail Y.;Petersen, Kathryn;Dye, James L.;Lefenfeld, Michael;Vogt, Paul F.;Jackson, James E.;,期刊:Organic Letters, 页码:5441-5444 , 文章类型: 研究论文,,卷期:2008年10-23]
  • A novel method for the desulfonation of secondary amines is were found to be useful solid-state reagents for the desulfonation of a range of N,N-disubstituted sulfonamides. M-SG reagents are room-temp.-stable free-flowi...
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