- Generic, Metal-Free Cross-Linking and Modification of Silicone Elastomers Using Click Ligation
[作者:Rambarran, T; Gonzaga, F; Brook, MA,期刊:Macromolecules, 页码:2276-2285 , 文章类型: Article,,卷期:2012年45-5]
- Silicone elastomers are widely used in a variety of biomaterials applications. Their high hydrophobicity can, in some cases, compromise their utility. There exist few convenient, efficient and metal-free processes to int...
- New Class of Biodegradable Polymers Formed from Reactions of an Inorganic Functional Group
[作者:Yoo, J; Kuruvilla, DJ; D'Mello, SR; Salem, AK; Bowden, NB,期刊:Macromolecules, 页码:2292-2300 , 文章类型: Article,,卷期:2012年45-5]
- Although numerous small molecules have been synthesized with sulfenamide bonds (R2N-SR), this is the first report of the synthesis of polysulfenamides. These polymers are readily synthesized at room temperature using sec...
- Highly Charged Conjugated Polymers with Polyphenylene Backbones and Poly(acrylic acid) Side Chains
[作者:Rugen-Penkalla, N; Klapper, M; Mullen, K,期刊:Macromolecules, 页码:2301-2311 , 文章类型: Article,,卷期:2012年45-5]
- A synthetic strategy to prepare various amphiphilic, conjugated graft copolymers by means of the grafting onto technique via click coupling reaction is described. In particular, amphiphilic, conjugated polyelectrolyte br...
- Side Chain Engineering of Polythiophene Derivatives with a Thienylene-Vinylene Conjugated Side Chain for Application in Polymer Solar Cells
[作者:Zhang, ZG; Zhang, SY; Min, J; Cui, CH; Geng, H; Shuai, ZG; Li, YF,期刊:Macromolecules, 页码:2312-2320 , 文章类型: Article,,卷期:2012年45-5]
- Two new conjugated side-chain isolated polythiophene derivatives, PT4TV and PT4TV-C, were designed and synthesized by copolymerization of thiophene unit with thienylene-vinylene (TV) conjugated side chain and unsubstitut...
- Controlled Chain-Growth Kumada Catalyst Transfer Polycondensation of a Conjugated Alternating Copolymer
[作者:Ono, RJ; Kang, SS; Bielawski, CW,期刊:Macromolecules, 页码:2321-2326 , 文章类型: Article,,卷期:2012年45-5]
- The Ni-catalyzed Kumada catalyst transfer polycondensation of a novel biaryl monomer, 2-(4-bromo-2,5-bis(2-ethylhexyloxy)phenyl)-5-chloromagnesiothiophene (2), afforded the respective pi-conjugated alternating copolymer ...
- Photo-Cross-Linkable Azide-Functionalized Polythiophene for Thermally Stable Bulk Heterojunction Solar Cells
[作者:Nam, CY; Qin, Y; Park, YS; Hlaing, H; Lu, XH; Ocko, BM; Black, CT; Grubbs, RB,期刊:Macromolecules, 页码:2338-2347 , 文章类型: Article,,卷期:2012年45-5]
- We have synthesized photo-cross-linkable azide-functionalized poly(3-hexylthiophene) to explore improvements in the thermal stability of bulk heterojunction solar cells. Exposing blends of photo-cross-linkable polythioph...
- Synthesis and Photovoltaic Properties of Copolymers Based on Benzo[1,2-b:4,5-b ']dithiophene and Thiophene with Different Conjugated Side Groups
[作者:Gu, ZJ; Tang, P; Zhao, B; Luo, H; Guo, X; Chen, HJ; Yu, G; Liu, XP; Shen, P; Tan, ST,期刊:Macromolecules, 页码:2359-2366 , 文章类型: Article,,卷期:2012年45-5]
- Three novel copolymers (PT-ID, PT-DTBT, and PT-DTBTID) of benzo[1,2-b:4,5-b']dithiophene and thiophene with different conjugated side groups (1,3-indanedione (ID), 4,7-dithien-5-yl-2,1,3-benzodiathiazole (DTBT), and DTBT...
- Introduction of Perylene Units for Enhanced Interchain Interaction in Conjugated Polymers for Organic Photovoltaic Devices
[作者:Kim, JH; Kim, HU; Mi, D; Jin, SH; Shin, WS; Yoon, SC; Kang, IN; Hwang, DH,期刊:Macromolecules, 页码:2367-2376 , 文章类型: Article,,卷期:2012年45-5]
- A series of semiconducting copolymers, poly[2,7-(9,9'-dioctylfluorene)-alt-5,5'-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (PFDTBT), poly[2,2'-(9,9-dioctyl-9H-fluorene-2,7-diyl)dithiophene-alt-5,5'-(4',7'-di-2-thien...
- Reactivity of Polymersome Encapsulated Hemoglobin with Physiologically Important Gaseous Ligands: Oxygen, Carbon Monoxide, and Nitric Oxide
[作者:Rameez, S; Banerjee, U; Fontes, J; Roth, A; Palmer, AF,期刊:Macromolecules, 页码:2385-2389 , 文章类型: Article,,卷期:2012年45-5]
- Two distinct preparations of amphiphilic diblock copolymer vesicles (i.e., polymersomes), composed of (poly(ethylene oxide)-poly(butadiene)) (PEO-PBD), with molecular weights of 1.8 and 10.4 kDa, offering different hydro...
- Glassy, Rouse, and Entanglement Dynamics As Revealed by Field Cycling H-1 NMR Relaxometry
[作者:Hofmann, M; Herrmann, A; Abou Elfadl, A; Kruk, D; Wohlfahrt, M; Rossler, EA,期刊:Macromolecules, 页码:2390-2401 , 文章类型: Article,,卷期:2012年45-5]
- Poly(propylene glycol), poly(isoprene), and poly(dimethlyl siloxane) (PDMS) of different molecular masses M are investigated by field-cycling H-1 NMR relaxometry to monitor the crossover from segmental dynamics, to Rouse...
- Phenyltrimethylammonium Functionalized Polysulfone Anion Exchange Membranes
[作者:Li, N; Zhang, Q; Wang, CY; Lee, YM; Guiver, MD,期刊:Macromolecules, 页码:2411-2419 , 文章类型: Article,,卷期:2012年45-5]
- Anion exchange membrane (AEM) materials were prepared from commercial polysulfone (PSf) by functionalization with tertiary amines via lithiation chemistry. By optimizing the reaction conditions, a degree of substitution ...
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