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  • Substrate Remote Control of Polymer Film Surface Mobility
    [作者:Siretanu, I; Chapel, JP; Drummond, C,期刊:Macromolecules, 页码:1001-1005 , 文章类型: Article,,卷期:2012年45-2]
  • Polymer segments at the surface of glassy polymer films remain mobile at temperatures below the glass transition temperature, T(g). This mobility, which is usually attributed to the access to a larger free volume by segm...
  • Kinetic Study for AB-Type Coupling Reaction of Tetra-Arm Polymers
    [作者:Nishi, K; Fujii, K; Chijiishi, M; Katsumoto, Y; Chung, U; Sakai, T; Shibayama, M,期刊:Macromolecules, 页码:1031-1036 , 文章类型: Article,,卷期:2012年45-2]
  • The reaction rate for the polycondensation in the Tetra-PEG gel system, i.e., A-B type coupling reaction between mutually reactive two four-arm polymers, has been studied by ATR-IR spectroscopy. It was found that (1) the...
  • Quantification of Branching in Model Three-Arm Star Polyethylene
    [作者:Ramachandran, R; Beaucage, G; Rai, DK; Lohse, DJ; Sun, T; Tsou, AH; Norman, A; Hadjichristidis, N,期刊:Macromolecules, 页码:1056-1061 , 文章类型: Article,,卷期:2012年45-2]
  • The versatility of a novel scaling approach in quantifying the structure of model well-defined 3-arm star polyethylene molecules is presented. Many commercial polyethylenes have long side branches, and the nature and qua...
  • New Correlations in Polymer Blend Miscibility
    [作者:White, RP; Lipson, JEG; Higgins, JS,期刊:Macromolecules, 页码:1076-1084 , 文章类型: Article,,卷期:2012年45-2]
  • We present new correlations revealed by our study of polymer mixture miscibility. Applying our simple lattice-based equation of state, we search for patterns in a large sample of experimental blends and uncover some intr...