- Rearrangement of 3-Deoxy-D-erythro-hexos-2-ulose in Aqueous Solution: NMR Evidence of Intramolecular 1,2-Hydrogen Transfer
[作者:ZHANG WENHUI; CARMICHAEL IAN; SERIANNI ANTHONY S,期刊:Journal of Organic Chemistry, 页码:8151-8158 , 文章类型: Article,,卷期:2011年76-20]
- Selective (13)C- and (2)H-labeling, and (13)C NMR spectroscopy, have been used to show that the 1,2-dicarbonyl compound (osone), 3-deoxy-D-erythro-hexos-2-ulose (3-deoxy-n-glucosone) (1; 3DG), degrades to 3-deoxy-D-ribo-...
- Photochemistry of S-Phenacyl Xanthates
[作者:VEETIL ANEESH TAZHE; SOLOMEK TOMAS; NGOY BOKOLOMBE PITCHOU; PAVLIKOVA NELA; HEGER DOMINIK; KLAN PETR,期刊:Journal of Organic Chemistry, 页码:8232-8242 , 文章类型: Article,,卷期:2011年76-20]
- Various synthetically readily accessible S-phenacyl xanthates are shown to undergo photoinitiated homolytic scission of the C-wS bond in the primary step. The resultant fragments, phenacyl and xanthic acid radicals, reco...
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