- Efficient Synthesis of a Sialic Acid a(2?)Galactose Building Block and Its Application to the Synthesis of Ganglioside GM3.
[作者:Liu, Yunpeng;Ruan, Xiaohong;Li, Xiangpeng;Li, Yingxia;,期刊:Journal of Organic Chemistry, 页码:4287-4290 , 文章类型: 研究论文,,卷期:2008年73-11]
- Glycosylation of various galactose derivs. with O-acetylated sialic acid N-phenyltrifluoroacetimidate as the donor was investigated. Efficient a(2,3)sialylation of galactose, with up to 73% yield and 8.4:1 stereoselecti...
- Gold(I)-Catalyzed Glycosidation of 1,2-Anhydrosugars.
[作者:Li, Yao;Tang, Pingping;Chen, Youxi;Yu, Biao;,期刊:Journal of Organic Chemistry, 页码:4323-4325 , 文章类型: 研究论文,,卷期:2008年73-11]
- Being able to increase the yield by >20% compared to the conventional use of anhyd. zinc chloride (>1 equiv) as a promoter, Ph3PAuOTf is disclosed to be a superior catalyst for the well-established glycosylation reaction...
- Highly Enantioselective Borane Reduction of Heteroaryl and Heterocyclic Ketoxime Ethers Catalyzed by Novel Spiroborate Ester Derived from Diphenylvalinol: Application to the Synthesis of Nicotine Analogues.
[作者:Huang, Kun;Merced, Francisco G.;Ortiz-Marciales, Margarita;Melendez, Hector J.;Correa, Wildeliz;De Jesus, Melvin;,期刊:Journal of Organic Chemistry, 页码:4017-4026 , 文章类型: 研究论文,,卷期:2008年73-11]
- An asym. synthesis for the prepn. of nonracemic amines bearing heterocyclic and heteroarom. rings is described. A variety of important enantiopure thionyl and arylalkyl primary amines were afforded by the borane-mediate...
- Design and Synthesis of Planar Chiral Heterocyclic Carbene Precursors Derived from [2.2]Paracyclophane.
[作者:Duan, Wenzeng;Ma, Yudao;Xia, Houqi;Liu, Xueying;Ma, Qingshuang;Sun, Junshan;,期刊:Journal of Organic Chemistry, 页码:4330-4333 , 文章类型: 研究论文,,卷期:2008年73-11]
- A unique family of planar chiral sym. N-heterocyclic carbene precursors with restricted flexibility derived from [2.2]paracyclophane were obtained by a new synthetic route. The resoln. of 4-amino-13-bromo[2.2]paracyclop...
- Stereoselective One-Pot Synthesis of Oxazolines.
[作者:Hajra, Saumen;Bar, Sukanta;Sinha, Debarshi;Maji, Biswajit;,期刊:Journal of Organic Chemistry, 页码:4320-4322 , 文章类型: 研究论文,,卷期:2008年73-11]
- Treatment of alkenes with NBS, a nitrile, NaHCO3 and water in the presence of Cu(OTf)2 or Zn(OTf)2 is reported to furnish oxazolines in one pot and good yields. E.g., reaction of trans-stilbene, MeCN, NBS, NaHCO3, and w...
- Rapid Access to Amino-Substituted Quinoline, (Di)Benzofuran, and Carbazole Heterocycles through an Aminobenzannulation Reaction.
[作者:Tiano, Martin;Belmont, Philippe;,期刊:Journal of Organic Chemistry, 页码:4101-4109 , 文章类型: 研究论文,,卷期:2008年73-11]
- A powerful aminobenzannulation reaction has been applied for the synthesis of amino-substituted quinolines, dibenzofurans, and carbazoles. The precursors are heterocycles bearing an acetyl group ortho to an internal alk...
- Enantioselective Baeyer-Villiger Oxidation Catalyzed by Palladium(II) Complexes with Chiral P,N-Ligands.
[作者:Malkov, Andrei V.;Friscourt, Frederic;Bell, Mark;Swarbrick, Martin E.;Kocovsky, Pavel;,期刊:Journal of Organic Chemistry, 页码:3996-4003 , 文章类型: 研究论文,,卷期:2008年73-11]
- Asym. Baeyer-Villiger reaction of sym. cyclobutanones with and the new terpene-derived P,N-ligand, e.g., I. The resulting lactones, e.g., II, were obtained in high yields and with good enantioselectivity (?1% ee).
- Total Synthesis of Solandelactones A, B, E, and F Exploiting a Tandem Petasis-Claisen Lactonization Strategy.
[作者:White, James D.;Lincoln, Christopher M.;Yang, Jongtae;Martin, William H. C.;Chan, David B.;,期刊:Journal of Organic Chemistry, 页码:4139-4150 , 文章类型: 研究论文,,卷期:2008年73-11]
- Solandelactones A, B, E, and F I (R = a-OH, R1 = H; R = b-OH, R1 = H; R = a-OH, R12 = bond; R = b-OH, R12 = bond, resp.) were synthesized using Nozaki-Hiyama-Kishi coupling of iododiene (3S,1E,5Z)-ICH:CHCH(OH)CH2CH:CH(CH...
- Synthesis of Hydrophobic Derivatives of the G-C Base for Rosette Nanotube Self-Assembly in Apolar Media.
[作者:Tikhomirov, Grigory;Oderinde, Martins;Makeiff, Darren;Mansouri, Ali;Lu, Weibing;Heirtzler, Fenton;Kwok, Daniel Y.;Fenniri, Hicham;,期刊:Journal of Organic Chemistry, 页码:4248-4251 , 文章类型: 研究论文,,卷期:2008年73-11]
- Eleven self-complementary G-C derivs. bearing hydrophobic moieties were synthesized and characterized. One representative deriv. I from this family was shown to self-assemble into rosette nanotubes in hexane and form La...
- Synthesis of 5,15-Diaryltetrabenzoporphyrins.
[作者:Filatov, Mikhail A.;Lebedev, Artem Y.;Vinogradov, Sergei A.;Cheprakov, Andrei V.;,期刊:Journal of Organic Chemistry, 页码:4175-4185 , 文章类型: 研究论文,,卷期:2008年73-11]
- A general method of synthesis of 5,15-diaryltetrabenzoporphyrins (Ar2TBPs), e.g. I, has been developed, based on 2 + 2 condensation of dipyrromethanes followed by oxidative aromatization. Two pathways to Ar2TBPs were in...
- Chemoselective Functionalization of 3,3'-Substituted BINOL Derivatives.
[作者:Coluccini, Carmine;Castelluccio, Antonio;Pasini, Dario;,期刊:Journal of Organic Chemistry, 页码:4237-4240 , 文章类型: 研究论文,,卷期:2008年73-11]
- An efficient chemoselective differentiation of vicinal phenolic and benzylic alcs. on optically active binaphthyl skeletons I (R = H, R1 = TBS, trityl, OCOPh; R = CH2CO2t-Bu, BOC, R1 = H) has been achieved via TBS protec...
- Stereoselective Synthesis of 3,3-Diarylacrylonitriles as Tubulin Polymerization Inhibitors.
[作者:Fang, Zhenglai;Song, Yunlong;Sarkar, Taradas;Hamel, Ernest;Fogler, William E.;Agoston, Gregory E.;Fanwick, Phillip E.;Cushman, Mark;,期刊:Journal of Organic Chemistry, 页码:4241-4244 , 文章类型: 研究论文,,卷期:2008年73-11]
- 22, 29 A series of 3,3-diarylacrylonitriles I (X = CMe, CCl, CCF3, N) were synthesized stereoselectively as tubulin polymn. inhibitors for potential use in cancer chemotherapy. This synthetic route features stannylcupra...
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