- Iminium Salts of w-Dithiafulvenylpolyenals: An Easy Entry to the Corresponding Aldehydes and Doubly Proaromatic Nonlinear Optic-phores.
[作者:Alias, Silvia;Andreu, Raquel;Blesa, Maria Jesus;Cerdan, Miguel Angel;Franco, Santiago;Garin, Javier;Lopez, Carolina;Orduna, Jesus;Sanz, Jorge;Alicante, Raquel;Villacampa, Belen;Allain, Magali;,期刊:Journal of Organic Chemistry, 页码:5890-5898 , 文章类型: 研究论文,,卷期:2008年73-15]
- A short, high-yielding route to w-dithiafulvenylpolyenals I (X = O; n = 2, 3) via the corresponding iminium salts I (X = NMe2) and starting from trimethyl-1,3-dithiolium tetrafluoroborate is reported. The Knoevenagel re...
- Combinatorial and Automated Synthesis of Phosphodiester Galactosyl Cluster on Solid Support by Click Chemistry Assisted by Microwaves.
[作者:Pourceau, Gwladys;Meyer, Albert;Vasseur, Jean-Jacques;Morvan, Francois;,期刊:Journal of Organic Chemistry, 页码:6014-6017 , 文章类型: 研究论文,,卷期:2008年73-15]
- Small libraries of di-, tri-, and tetra-galactosyl clusters were efficiently synthesized using combinatorial methodol., on solid support, by click chem. assisted by microwaves, starting from different poly alkyne DNA-bas...
- New Picropodophyllin Analogs via Palladium-Catalyzed Allylic Alkylation-Hiyama Cross-Coupling Sequences.
[作者:Vitale, Maxime;Prestat, Guillaume;Lopes, David;Madec, David;Kammerer, Claire;Poli, Giovanni;Girnita, Leonard;,期刊:Journal of Organic Chemistry, 页码:5795-5805 , 文章类型: 研究论文,,卷期:2008年73-15]
- Unsatd. malonyl esters underwent Pd-catalyzed intramol. allylic alkylation to give 4-vinyl-substituted g-lactones. In contrast to the formerly studied cyclization of malonamides, this reaction could be achieved only wit...
- Tailoring a Bacteriochlorin Building Block with Cationic, Amphipathic, or Lipophilic Substituents.
[作者:Ruzie, Christian;Krayer, Michael;Balasubramanian, Thiagarajan;Lindsey, Jonathan S.;,期刊:Journal of Organic Chemistry, 页码:5806-5820 , 文章类型: 研究论文,,卷期:2008年73-15]
- Bacteriochlorins are attractive candidates for photodynamic therapy (PDT) of diverse medical indications owing to their strong absorption in the near-IR (NIR) region, but their use has been stymied by lack of access to s...
- Rational Combination of Two Privileged Chiral Backbones: Highly Efficient Organocatalysts for Asymmetric Direct Aldol Reactions between Aromatic Aldehydes and Acyclic Ketones.
[作者:Chen, Jia-Rong;An, Xiao-Lei;Zhu, Xiao-Yu;Wang, Xu-Fan;Xiao, Wen-Jing;,期刊:Journal of Organic Chemistry, 页码:6006-6009 , 文章类型: 研究论文,,卷期:2008年73-15]
- A new class of organocatalysts has been designed by rational combination of proline with cinchona alkaloids. A chiral amine, prepd. from L-proline and cinchonidine, has been found to be an efficient catalyst for the dir...
- Cinnamoyl Inhibitors of Tissue Transglutaminase.
[作者:Pardin, Christophe;Pelletier, Joelle N.;Lubell, William D.;Keillor, Jeffrey W.;,期刊:Journal of Organic Chemistry, 页码:5766-5775 , 文章类型: 研究论文,,卷期:2008年73-15]
- 7, 75 Transglutaminases (TGases) catalyze the intermol. crosslinking of certain proteins and tissue TGases (TG2) are involved in diverse biol. processes. Unregulated, high TGase activities have been implicated in severa...
- Single-Isomer Trisubstituted Olefins from a Novel Reaction of (E)-b-Chloro-a-iodo-a,b-unsaturated Esters and Amides.
[作者:Simard-Mercier, Julie;Jiang, Jojo Liu;Ho, Michael L.;Flynn, Alison B.;Ogilvie, William W.;,期刊:Journal of Organic Chemistry, 页码:5899-5906 , 文章类型: 研究论文,,卷期:2008年73-15]
- (E)-b-Chloro-a-iodo-a,b-unsatd. esters are converted to single isomer trisubstituted olefins bearing three different carbon substituents by cross-coupling under reflux. Mechanistic investigations suggest that this proce...
- Synthesis, Structure, and Transannular p-p Interaction of Three- and Four-Layered [3.3]Paracyclophanes. [Erratum to document cited in CA149:053562].
[作者:Shibahara, Masahiko;Watanabe, Motonori;Iwanaga, Tetsuo;Matsumoto, Taisuke;Ideta, Keiko;Shinmyozu, Teruo;,期刊:Journal of Organic Chemistry, 页码:6052-6052 , 文章类型: 研究论文,,卷期:2008年73-15]
- On page 4441, in column 2, in line 19, "EbsMIC 7" should read "EbsMIC".
- Nucleophilic Fluoroalkylation of a,b-Enones, Arynes, and Activated Alkynes with Fluorinated Sulfones: Probing the Hard/Soft Nature of Fluorinated Carbanions.
[作者:Ni, Chuanfa;Zhang, Laijun;Hu, Jinbo;,期刊:Journal of Organic Chemistry, 页码:5699-5713 , 文章类型: 研究论文,,卷期:2008年73-15]
- The nucleophilic fluoroalkylation of a,b-enones, arynes, and activated alkynes with fluorinated sulfones is described. It was found that for acyclic a,b-enones, although the reaction medium and the structure of the enon...
- Enantioselective Synthesis of b-Aryl-g-amino Acid Derivatives via Cu-Catalyzed Asymmetric 1,4-Reductions of g-Phthalimido-Substituted a,b-Unsaturated Carboxylic Acid Esters.
[作者:Deng, Jun;Hu, Xiang-Ping;Huang, Jia-Di;Yu, Sai-Bo;Wang, Dao-Yong;Duan, Zheng-Chao;Zheng, Zhuo;,期刊:Journal of Organic Chemistry, 页码:6022-6024 , 文章类型: 研究论文,,卷期:2008年73-15]
- A series of chiral b-aryl-substituted g-amino butyric acid derivs. I (R = 4-FC6H4, 3-MeOC6H4, 2-thienyl, etc.) were synthesized in good enantioselectivities via the Cu-catalyzed asym. conjugate redn. of g-phthalimido-a,b...
- Rapid and Efficient Pd-Catalyzed Sonogashira Coupling of Aryl Chlorides.
[作者:Huang, He;Liu, Hong;Jiang, Hualiang;Chen, Kaixian;,期刊:Journal of Organic Chemistry, 页码:6037-6040 , 文章类型: 研究论文,,卷期:2008年73-15]
- An efficient and effective microwave-assisted cross-coupling of terminal alkynes with various aryl chlorides including sterically hindered, electron-rich, electron-neutral, and electron-deficient aryl chloride is develop...
- Total synthesis of (?-flustramines A and C, (?-flustramide A, and (-)- and (+)-debromoflustramines A.
[作者:Kawasaki, Tomomi;Shinada, Masashi;Ohzono, Mayu;Ogawa, Atsuyo;Terashima, Romi;Sakamoto, Masanori;,期刊:Journal of Organic Chemistry, 页码:5959-5964 , 文章类型: 研究论文,,卷期:2008年73-15]
- Here we describe the efficient total synthesis of the three title hexahydropyrrolo[2,3-b]indole alkaloids and debromo deriv. from readily available indolin-3-ones using key domino reactions, olefination-isomerization-Cla...
- A Computational Study of Multicomponent Orbital Interactions during the Cyclization of Silyl, Germyl, and Stannyl Radicals onto C-N and C-O Multiple Bonds.
[作者:Wille, Uta;Tan, Jeremy C.-S.;Mucke, Eva-Katrin;,期刊:Journal of Organic Chemistry, 页码:5821-5830 , 文章类型: 研究论文,,卷期:2008年73-15]
- BHandHLYP/6-311G** and BHandHLYP/DZP computations of the potential surface of Si-, Ge-, and Sn-radical cyclizations onto the imine double bond reveal that these reactions proceed through simultaneous SOMO ?p*, LPN ?SOMO,...
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